The UConn Soil Nutrient Analysis Lab tests for and analyzes multiple soil parameters; but none as critical, and as often overlooked, as pH. Soil pH plays a crucial role in the growth of vegetation planted, as well as ground water quality. Before we start talking about soil pH, I think it is a good idea to try to define what exactly pH is, and how it is determined.
When most of us think of pH, a pool probably comes to mind. I remember growing up, watching my mother apply different chemicals to our pool, and impatiently wondering why I had to wait to go swimming. She would tell me that she was adjusting the pH of the water to ensure it was safe to swim in. The basic understanding is that pH is tells us how acidic, neutral, or alkaline something is. To get a little more technical, pH is the measurement of the activity of Hydrogen Ions (H+) in an aqueous solution. The equation for determining and quantifying pH is:
pH = -log10 (aH+)
(aH+= Hydrogen Ion Activity in Moles/L)
We express pH on a logarithmic scale of 0-14, where 0-6 is considered “acidic”, 7 is “neutral”, and 8-14 is “basic”.
Mineral soil pH values generally range from 3.0 – 10.0. There are numerous factors that determine soil pH including climate, parent material, weathering, relief, and time. Texture and organic matter content also influence soil pH. Most Connecticut soils are naturally acidic. Nutrient availability is directly influenced by pH with most plants (with some exceptions) thriving at pH values between 6 and 7. A majority of nutrients are available within this range.
Our lab measures pH using an 1:1 soil-to-DI water ratio. The saturated soil paste is mixed, then is analyzed using a glass electrode and a pH meter. We calibrate our meter using 2 solutions with known pH values, 4 and 7. We use these values because we expect most Connecticut soils to fall within this range. Once the initial pH value is obtained, a buffering agent is added. In our lab we use the Modified Mehlich Buffer. A second pH reading is obtained, and from these two values plus crop information, we are able to make limestone and/or sulfur recommendations.
The Buffering Capacity of a soil is the resistance it has to change in pH. Soil buffering is controlled by its Cation-Exchange-Capacity, Aluminum content (in acidic soils), organic matter content, and texture. A soil with a lot of organic matter and clay will have a higher buffering capacity than one with little organic matter that is mostly sandy.
If the soil pH is lower than the target range for a particular plant, limestone would be recommended. Whether you use pelletized, ground or granular limestone, the application rate would be the same. Once the target pH is reached, a maintenance application of 50 lbs/1000 sq ft would be applied every other year to maintain it.
If the soil pH is higher than desired, sulfur recommendations are made. Typically only powdered sulfur is available locally but granular sulfur could be mail ordered. Aluminum sulfate can be substituted for sulfur and used at a higher rate. Check out this listof preferred pH ranges for many common plants.
Monitoring your soil pH is essential to ensure that it is falling within the range best suited for the vegetation you are growing. The Standard Nutrient Analysis performed at our lab gives you a pH value, a buffer pH value, a lime/sulfur recommendation, available micro & macro nutrient levels, and a fertilizer recommendation. For more information on pH, you can contact Dawn or myself (Joe) at the UConn Soil Nutrient Analysis Lab (www.soiltest.uconn.edu). Test, don’t guess!
By Joe C.